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Question: Aniline reacts with which of these to form Schiff base...

Aniline reacts with which of these to form Schiff base

A

Acetic acid

B

Benzaldehyde

C

Acetone

D

NH3NH_{3}

Answer

Benzaldehyde

Explanation

Solution

Aniline reacts with benzaldehyde and forms Schiff's base (benzal aniline) or anils.

C6H5NH2+O=CHC6H5ΔH2OC6H5N=CHC6H5\mathbf{C}_{\mathbf{6}}\mathbf{H}_{\mathbf{5}}\mathbf{-}\mathbf{N}\mathbf{H}_{\mathbf{2}}\mathbf{+ O = CH}\mathbf{C}_{\mathbf{6}}\mathbf{H}_{\mathbf{5}}\underset{\mathbf{-}\mathbf{H}_{\mathbf{2}}\mathbf{O}}{\overset{\mathbf{\quad\Delta\quad}}{\rightarrow}}\mathbf{C}_{\mathbf{6}}\mathbf{H}_{\mathbf{5}}\mathbf{N = CH}\mathbf{C}_{\mathbf{6}}\mathbf{H}_{\mathbf{5}}

Benzylidine aniline