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Question

Chemistry Question on The solid state

Analysis shows that an oxide ore of nickel has formula Ni0.98O1.00Ni_{0.98} O_{1.00} The percentage of nickel as Ni3+Ni^{3+} ions is nearly

A

2

B

96

C

4

D

98

Answer

4

Explanation

Solution

Let no. of nickel ions =98= 98 \therefore No. of oxide ions =100= 100 Total negative charge on O2O^{2-} ions =2×100=200= 2 \times 100 = 200 Let no. of Ni3+Ni^{3+} ions =x= x \therefore No. of Ni2+Ni^{2+} ions =98x= 98 - x x×3+(98x)×2=200x \times 3 + (98 - x) \times 2 = 200 3x2x=2001963x - 2x = 200 - 196 x=4x = 4 Percentage of nickel as Ni3+=498×100Ni^{3+} = \frac{4}{98} \times 100 =4.08 = 4.08