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Question

Chemistry Question on Thermodynamics

An ideal gas undergoes isothermal expansion at constant pressure. During the process :

A

enthalpy increases but entropy decreases.

B

enthalpy remains constant but entropy increases

C

enthalpy decreases but entropy increases.

D

Both enthalpy and entropy remain constant .

Answer

Both enthalpy and entropy remain constant .

Explanation

Solution

ΔH=nCpΔT=0\Delta H = nC _{ p } \Delta T =0 ΔS=nRln(Vf/Vi)0\Delta S = nR \ln \left( V _{ f } / V _{ i }\right) \geq \,0