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Question

Chemistry Question on Thermodynamics

An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If TiT_i is the initial temperature and TfT_f is the final temperature, which of the following statements is correct ?

A

(Tf)irrev>(Tf)rev\left(T_{f}\right)_{irrev} > \left(T_{f}\right)_{rev}

B

Tf>TiT_f > T_i for reversible process but Tf=TiT_f = T_i for irreversible process

C

(Tf)rev>(Tf)irrev\left(T_{f}\right)_{rev} > \left(T_{f}\right)_{irrev}

D

Tf=TiT_f = T_i for both reversible and irreversible processes

Answer

(Tf)irrev>(Tf)rev\left(T_{f}\right)_{irrev} > \left(T_{f}\right)_{rev}

Explanation

Solution

Tf(irreversible)>Tf(reversible)T _{f\,\left(irreversible\right)} > T_{f\,\left(reversible\right)} It is an adiabatic expansion and W (rev) is maximum.