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Question: An ideal gas at (P,V,T) is expanding adiabatically to 5.66 times the volume and half the temperature...

An ideal gas at (P,V,T) is expanding adiabatically to 5.66 times the volume and half the temperature. The degree of freedom f of the gas and work done W by the gas –

A

W = 0, f = 5

B

W = PV, f = 7

C

W =2523\frac{25}{23}P, f = 7

D

W =2523\frac{25}{23}PV, f = 5

Answer

W =2523\frac{25}{23}PV, f = 5

Explanation

Solution

For an adiabatic process

T1V1γ1V_{1}^{\gamma - 1} = T2V2γ1V_{2}^{\gamma - 1}

Given T2 =T12\frac{T_{1}}{2} and

V2 = 5.66 V1

T1T2\frac{T_{1}}{T_{2}}=(V2V1)γ1\left( \frac{V_{2}}{V_{1}} \right)^{\gamma - 1}

2 = (5.66)g–1

or g = 1.458

Hence gas is diatomic having f = 5.

W =P2V2P1V1r1\frac{P_{2}V_{2} - P_{1}V_{1}}{r - 1} andP2V2T2\frac{P_{2}V_{2}}{T_{2}}=P1V1T1\frac{P_{1}V_{1}}{T_{1}}

=5.6611.32P1V1P1V11.461\frac{\frac{5.66}{11.32}P_{1}V_{1} - P_{1}V_{1}}{1.46 - 1}

P2 =P111.32\frac{P_{1}}{11.32} and

V2 = 5.66 V1

=0.5P1V10.46\frac{0.5P_{1}V_{1}}{0.46}=[25PV23]\left\lbrack \frac{25PV}{23} \right\rbrack