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Question: An ice cube of mass 0.1 kg at 0°C is placed in an isolated container which is at 227°C. The specific...

An ice cube of mass 0.1 kg at 0°C is placed in an isolated container which is at 227°C. The specific heat s of the container varies with temperature T according to the empirical relation s = A + BT, where A =100 calkg1K1kg^{- 1}K^{- 1}and B=2×102calkg1B = 2 \times 10^{- 2}calkg^{- 1} If the final temperature of the container is 27°C, the mass of the container is

(Latent heat of fusion of water =8×104calkg1= 8 \times 10^{4}calkg^{- 1} specefic heat of water =103Calkg1k1= 10^{3}Calkg^{- 1}k^{- 1})

A

0.495 kg

B

0.595 kg

C

0.695 kg

D

0.795 kg

Answer

0.495 kg

Explanation

Solution

Heat lost by container

=500300mC= - \int_{500}^{300}m_{C} (A+BT)dT

=mC[AT+BT22]500300=21600mC= - m_{C}\left\lbrack AT + \frac{BT^{2}}{2} \right\rbrack_{500}^{300} = 21600m_{C}

Heat gained by ice

=miceL+miceswaterΔT= m_{ice}L + m_{ice}s_{water}\Delta T

=0.1×8×104+0.1×103×27= 0.1 \times 8 \times 10^{4} + 0.1 \times 10^{3} \times 27

= 10700 cal

According to principle of calorimetry Heat lost by constainer = Heat gained by ice

21600mc=10700m_{c} = 10700

Or mc=0.495kgm_{c} = 0.495kg