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Question

Chemistry Question on Chemical Kinetics

An exothermic chemical reaction proceeds by two stages. Reactants >[Stage1]{ ->[Stage\, 1] } Intermediate >[Stage2]{ ->[Stage\, 2] } Products The activation energy of state II is 50kJ50 \,kJ mol1mol^{-1}. The overall enthalpy change for the reaction is 100kJ-100 \,kJ mol1mol^{-1}. Which diagram could represent the energy level diagram for the reaction?

A

B

C

D

Answer

Explanation

Solution

Diagram (c)\left(c\right) represents exothermic reaction with
EaE_{a} =200150=50kJ=200-150=50\, kJ mol1mol^{-1} and
ΔH\Delta H =50150=100kJ=50-150=-100\, kJ mol1mol^{-1}