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Question

Chemistry Question on Thermodynamics

An endothermic reaction is found to have +ve+ve entropy change. The reaction will be

A

possible at high temperature

B

possible only at low temperature

C

not possible at any temperature

D

possible at any temperature.

Answer

possible at high temperature

Explanation

Solution

Given, ΔS=+ve\Delta S = { + ve} and ΔH=+ve\Delta H = {+ve}
Now, ΔG=ΔHTΔS\Delta G = \Delta H - T \Delta S
For a reaction to be spontaneous, ΔG\Delta G should be -ve, which is possible only at high temperature i.e. when TΔS>ΔHT\Delta S > \Delta H