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Question: An elements X burns in nitrogen to give a compound Y which on reaction with water gives a compound Z...

An elements X burns in nitrogen to give a compound Y which on reaction with water gives a compound Z and a gas with a pungent smell. Z can be used during construction nd white washing. When excess of CO2CO_{2} is bubbled through Z, a compounds p is formed which on heating decomposes to give a colourless, odourless gas. Identify X, Y, Z and P.

XYZP
A

| Ca | | | Ca3N2Ca_{3}N_{2} | | | | Ca(OH)2Ca(OH)_{2} | | | Ca(HCO3)2Ca(HCO_{3})_{2} | | | | |

B

| Mg | | | MgO | | | | Mg(OH)2Mg(OH)_{2} | | | MgCO3MgCO_{3} | | | | |

C

| Ca | | | Ca3N2Ca_{3}N_{2} | | | | Ca(OH)2Ca(OH)_{2} | | | CaCO3CaCO_{3} | | | | |

D

| Ca | | | CaO | | | | Ca(OH)2Ca(OH)_{2} | | | Ca(HCO3)2Ca(HCO_{3})_{2} | | | | |

Explanation

Solution

: 3Ca(X)+N2Ca3N2(Y)\underset{(X)}{3Ca} + N_{2} \rightarrow \underset{(Y)}{Ca_{3}N_{2}}

Ca3N2+6H2O3Ca(OH)2+2NH3(gaswithapungentsmell)Ca_{3}N_{2} + 6H_{2}O \rightarrow 3Ca(OH)_{2} + \underset{(gaswithapungentsmell)}{2NH_{3}}

Ca(OH)2(Z)+CO2excessCa(HCO3)2(P)\underset{(Z)}{Ca(OH)_{2}} + \underset{excess}{CO_{2}} \rightarrow \underset{(P)}{Ca(HCO_{3})_{2}}

Ca(HCO3)2(P)heatCaCO3+H2O+CO2\underset{(P)}{Ca(HCO_{3})_{2}}\overset{\quad heat\quad}{\rightarrow}CaCO_{3} + H_{2}O + CO_{2}