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Question: An elemental crystal has a density of 8570 kg/m3. The packing efficiency is 0.68. The closest distan...

An elemental crystal has a density of 8570 kg/m3. The packing efficiency is 0.68. The closest distance of approach between neighbouring atom is 2.86 Å. What is the mass of one atom approximately ?

A

29 amu

B

39 amu

C

63 amu

D

93 amu

Answer

93 amu

Explanation

Solution

The packing efficiency = 0.68, means the given lattice is BCC.

The closest distance of approach = 2r

2r = 2.86 A0 = 3a2\frac{\sqrt{3}a}{2} or a = 2×2.863\frac{2 \times 2.86}{\sqrt{3}}= 3.30 Aº.

Let at. wt. of the element = a

\2×a36×1023×(3.3)3×1024\frac{2 \times a}{36 \times 10^{23} \times (3.3)^{3} \times 10^{–24}}= 8.57

a = 8.57 × 3 × (3.3)3 × 0.1 = 92.39 ~ 93