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Question

Chemistry Question on The solid state

An element has a body centered cubic (bcc) structure with a cell edge of 288 pm. The atomic radiusis:

A

34×288pm\frac{\sqrt{3}}{4}\times 288 \,pm

B

24×288pm\frac{\sqrt{2}}{4}\times 288 \,pm

C

43×288pm\frac{4}{\sqrt{3}}\times 288 \,pm

D

42×288pm\frac{4}{\sqrt{2}}\times 288 \,pm

Answer

34×288pm\frac{\sqrt{3}}{4}\times 288 \,pm

Explanation

Solution

In bcc unit cell, atoms lying along a body diagonal touch each other
Length of body diagonal =3a=\sqrt{3}a
3a=4r\sqrt{3}a=4r
r=34ar=\frac{\sqrt{3}}{4}a
As a=288pma=288\,pm
r=34×288Pm\therefore r=\frac{\sqrt{3}}{4}\times288Pm