Question
Question: An electron of stationary hydrogen atom passes from the fifth energy level to the ground level. The ...
An electron of stationary hydrogen atom passes from the fifth energy level to the ground level. The velocity that the atom of mass m acquired a result of photon emission will be:
(R is Rydberg constant and h is Planck’s constant)
A.24hR25m
B. 25hR24m
C. 25m24hR
D. 24m25hR
Solution
Use Rydberg formula to determine the wavelength of the emitted photon. Then use the formula for energy of the photon to determine the energy of the emitted photon. Use the relation between momentum and energy of the photon to determine the velocity of the emitted photon.
Formula Used: The expression for the Rydberg formula is
λ1=R(n121−n221) …… (1)
Here, λ is the wavelength of the photon emitted by an electron jumping from level n2to level n1 and R is the Rydberg constant.
The energy E of a photon is given by
E=λhc …… (2)
Here, h is Planck’s constant, c is the speed of light and λ is the wavelength of the photon.
The energy E of photon in terms of momentum P is
P=cE …… (3)
Here, c is the speed of light.
The momentum P of an object is given by
P=mv …… (4)
Here, m is the mass of an object and v is the velocity of the object.
Complete step by step answer:
An electron of a stationary hydrogen atom passes from the fifth energy level to the ground level.
Determine the wavelength λ of the photon when the electron jumps from the fifth energy level to the ground level.
The ground level of the hydrogen atom is denoted by 1.
Substitute 1 for n1 and 5 for n2 in equation (1).
λ1=R(121−521)
⇒λ1=R(1−251)
⇒λ1=R(2525−1)
⇒λ=24R25
Hence, the wavelength of the emitted photon is 24R25.
Determine the energy of the emitted photon.
Substitute 24R25 for λ in equation (2).
E=2524Rhc
Substitute cE for P in equation (4).
cE=mv
Substitute 2524Rhc for E in the above equation.
c2524Rhc=mv
⇒2524Rh=mv
Rearrange the above equation for the velocity v of the emitted photon.
v=25m24hR
Therefore, the velocity of the emitted photon will be 25m24hR.
Hence, the correct option is C.
Note: One can also determine the velocity of the emitted photon using the law of conservation of linear momentum after determining the wavelength of the emitted photon.