Question
Question: An electron, in a hydrogen atom, in its ground state absorbs \[1.5\]times as much energy as the mini...
An electron, in a hydrogen atom, in its ground state absorbs 1.5times as much energy as the minimum required for its escape i.e.., 13.6eV from the atom. Calculate the value of λ for the emitted electron.
A.4.69A0
B.3.9A0
C.7.9A0
D.46.9A0
Solution
The energy absorbed is the product of 1.5 times of 13.6eV , as the minimum energy is 13.6eV From this value of energy absorbed the kinetic energy will be determined. Substituting the kinetic energy value in the de broglie wavelength formula gives the value of wavelength.
Complete answer:
Given that an electron in a hydrogen atom absorbs 1.5times as much energy as the minimum required for its escape i.e.., 13.6eV from the atom
The amount of energy absorbed by an electron will be 1.5×13.6=20.4eV
Out of this 20.4eV of energy 20.4−13.6=6.8eV of energy will be converted into kinetic energy.
Convert this energy into joules which will be 6.8×1.6×10−19 joules
The equation for the kinetic energy is given as E=21mv2
The velocity will be v=m2E
The de broglie wavelength will be given as λ=mvh
Substitute the value of velocity in the above equation, will get λ=2Emh
h is Planck’s constant has the value of 6.62×10−34Js
m is mass of electron has the value of 9.1×10−31kg
Substitute the values in the wavelength formula
λ=2×6.8×1.6×10−19×9.1×10−316.62×10−34=14.076.62×10−34=4.69×10−10m
While converts metres into angstroms, one angstrom will be equal to 4.69A0
Option A is the correct one.
Note:
The energy of the electron should be in column but not in electron volts, conversion must be made from electron volt to coulomb. The mass of the electron should be in kilograms. Finally, the obtained wavelength is in metres, it should be converted into angstroms. Thus, units must check while deriving the wavelength.