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Question

Physical Chemistry Question on Molecular structure and Chemical bonding

Among the following, the correct statement(s) is (are) :

A

the normalization factor of a Slater determinant for a 3-electron atom is 13\sqrt{\frac{1}{3}}.

B

the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom.

C

the energy separation between any two adjacent states is same for a harmonic oscillator, while it is different for a rigid rotor.

D

the magnitude of the total spin angular momentum of an α electron is the negative of that of a ẞ electron.

Answer

the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom.

Explanation

Solution

The correct option is (B) : the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom and (C) : the energy separation between any two adjacent states is same for a harmonic oscillator, while it is different for a rigid rotor.