Question
Physical Chemistry Question on Molecular structure and Chemical bonding
Among the following, the correct statement(s) is (are) :
the normalization factor of a Slater determinant for a 3-electron atom is 31.
the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom.
the energy separation between any two adjacent states is same for a harmonic oscillator, while it is different for a rigid rotor.
the magnitude of the total spin angular momentum of an α electron is the negative of that of a ẞ electron.
the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom.
Solution
The correct option is (B) : the number of nodes in the radial wave function of 3s orbital of a hydrogen atom is the same as the number of nodes in the angular wave function of a 4d orbital of hydrogen atom and (C) : the energy separation between any two adjacent states is same for a harmonic oscillator, while it is different for a rigid rotor.