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Question: Among \({\text{PbS,}}\,{\text{CuS,}}\,{\text{HgS,}}\,{\text{MnS,}}\,{\text{A}}{{\text{g}}_{\text{2}}...

Among PbS,CuS,HgS,MnS,Ag2S,NiS,CoS,Bi2S3{\text{PbS,}}\,{\text{CuS,}}\,{\text{HgS,}}\,{\text{MnS,}}\,{\text{A}}{{\text{g}}_{\text{2}}}{\text{S,}}\,{\text{NiS,}}\,{\text{CoS,}}\,{\text{B}}{{\text{i}}_{\text{2}}}{{\text{S}}_{\text{3}}}and SnS2{\text{Sn}}{{\text{S}}_{\text{2}}}the total number of black coloured sulphides are:
A) 66
B) 77
C) 88
D) 99

Explanation

Solution

Hint : Sulphide is a sulphur inorganic anion with the chemical formula S2 - {{\text{S}}^{{\text{2 - }}}} or a compound containing one or more S2 - {{\text{S}}^{{\text{2 - }}}} ions. H2S{{\text{H}}_{\text{2}}}{\text{S}} reacts with CuCl2{\text{CuC}}{{\text{l}}_{\text{2}}} to produce a black sulphide. Sulphide salt solutions are corrosive. Large families of inorganic and organic compounds, such as lead sulphide and dimethyl sulphide, are classified as sulphides.

Complete Step By Step Answer:
There are a total of six black coloured sulphides. This includes the following:
PbS,CuS,HgS,NiS,CoS,Bi2S3.{\text{PbS,}}\,{\text{CuS,}}\,{\text{HgS,}}\,{\text{NiS,}}\,{\text{CoS,}}\,{\text{B}}{{\text{i}}_{\text{2}}}{{\text{S}}_{\text{3}}}{\text{.}}
PbS:{\text{PbS}}\,{\text{:}}
Lead (II) sulphide is a black-colored inorganic compound with the formula PbS{\text{PbS}}. Galena is the most common ore and the most effective lead compound. It's a semiconducting substance with specific applications.
CuS :{\text{CuS :}}
Copper monosulfide is a black-colored chemical compound made up of copper and sulphur.
HgS{\text{HgS}}:
Mercury (II) sulphide, is a black crystalline solid that is primarily used as a pigment in paints, rubber, and plastics.
NiS{\text{NiS}}:
Nickel sulphide has the formula NiS{\text{NiS}} and is an inorganic compound. It's a black solid made from nickel (II) salts treated with hydrogen sulphide.
CoS{\text{CoS}}:
Chemical compounds with the formula CoxSyC{o_x}{S_y}are known as cobalt sulphide. Cobalt sulphides are black, semiconducting, insoluble in water, and nonstoichiometric in nature.
Bi2S3:B{i_2}{S_3}:
Bismuth (III) sulphide is a black-coloured chemical compound of bismuth and sulphur. Bismuthinite is the mineral type of bismuth.
The crystalline form of Bi2S3B{i_2}{S_3} is dark brown, but the precipitate obtained is black.
Hence, the total number of black coloured sulphides are 66.

Note :
Solid sulphides are formed when aqueous solutions of transition metal cations react with sulphide sources. Many of these inorganic sulphides are bound to minerals of similar compositions and have a poor solubility in water.