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Question

Chemistry Question on Chemical bonding and molecular structure

Among LiCl,BeCl2,BCl3LiCl, BeCl_2, BCl_3 and CCl4CCl_4 , the covalent bond character follows the order

A

LiCl<BeCl2>BCl3>CCl4LiCl < BeCl_2 >BCl_3 >CCl_4

B

LiCl<BeCl2<BCl3>CCl4LiCl < BeCl_2 < BCl_3 >CCl_4

C

LiCl<BeCl2<BCl3<CCl4LiCl < BeCl_2 < BCl_3 < CCl_4

D

LiCl>BeCl2>BCl3>CCl4LiCl > BeCl_2 > BCl_3 >CCl_4

Answer

LiCl<BeCl2<BCl3<CCl4LiCl < BeCl_2 < BCl_3 < CCl_4

Explanation

Solution

The electronegativity increases from left to right in any period, so the electronegativity follows the order
\hspace26mm Li < Be < B < C and hence, the covalent character of chlorides of
these elements increase from Li to C because size of cation left to right decreases and according to Fajans- rule covalent character increases.