Question
Chemistry Question on Chemical bonding and molecular structure
Among LiCl,BeCl2,BCl3and CCl4 , the covalent bond character follows the order
A
LiCl<BeCl2>BCl3>CCl4
B
LiCl<BeCl2<BCl3>CCl4
C
LiCl<BeCl2<BCl3<CCl4
D
LiCl>BeCl2>BCl3>CCl4
Answer
LiCl<BeCl2<BCl3<CCl4
Explanation
Solution
The electronegativity increases from left to right in any period, so the electronegativity follows the order
\hspace26mm Li < Be < B < C and hence, the covalent character of chlorides of
these elements increase from Li to C because size of cation left to right decreases and according to Fajans- rule covalent character increases.