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Question

Chemistry Question on Molecular Orbital Theory

Among KO2KO_2, AlO2AlO_2^- , BaO2BaO_2 and NO2+NO_2^+, unpaired electron is present in

A

NO2+NO_2^+ and BaO2BaO_2

B

KO2KO_2, and AlO2AlO_2^-

C

Only KO2KO_2

D

Only BaO2BaO_2

Answer

Only KO2KO_2

Explanation

Solution

The correct option is(C): KO2.

Number of electrons has to be calculated:

NO2+: 5+6(2)-1 =16 electrons

AlO2- = 3+6(2) +1 = 16 electrons

BaO2 = 2+6(2)= 14 electrons

KO2 =1 +6(2) = 13 electrons

All the compounds have paired electrons except KO2. Therefore, the answer is KO2