Question
Chemistry Question on coordination compounds
Aluminium reacts with NaOH and forms compound 'X'. If the coordination number of aluminium in 'X' is 6, the correct formula of X is
A
[Al(H2O)4(OH)2]+
B
[Al(H2O)3(OH)3]
C
[Al(H2O)2(OH)4]−
D
[Al(H2O)6](OH)3
Answer
[Al(H2O)2(OH)4]−
Explanation
Solution
2Al+2NaOH+2H2O⟶Sodium meta aluminate2NaAlO3+3H2
Sodium meta alurninate, thus formed, is soluble in water and changes into the complex [Al(H2O)2(OH)4]−in which coordination number of Al is 6.