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Question: Aluminium chloride exists as dimer, Al2Cl6 in solid state as well as in solution of non-polar solven...

Aluminium chloride exists as dimer, Al2Cl6 in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives :

A

[Al(OH)6]3– + 3HCl

B

[Al(H2O)6]3+ + 3Cl–

C

Al3+ + 3Cl–

D

Al2O3 + 6HCl

Answer

Al(H2O)6Al(H2O)63+ + 3Cl–

Explanation

Solution

AlCl3 + 6H2O \rightleftharpoons [Al(H2O)6]3+ + 3CI–