Question
Question: Addition of \({ SnCl }_{ 2 }\) to \({ HgCl }_{ 2 }\) gives ppt: A. White turning to grey B. Blac...
Addition of SnCl2 to HgCl2 gives ppt:
A. White turning to grey
B. Black turning to white
C. White turning to red
D. None of these
Solution
Redox reactions are those reactions in which oxidation and reduction occur simultaneously. The reaction of SnCl2 with HgCl2 is an oxidation-reduction reaction.
Complete answer:
When SnCl2 reacts with HgCl2, the following reaction will take place:
2HgCl2+SnCl2→2HgCl+SnCl4
This addition of SnCl2 to HgCl2 gives white turning to a grey ppt. HgCl2 formed is white.
On further reaction, HgCl is converted to Hg which is grey due to further reduction.
In this reaction, SnCl2 acts as an oxidizing agent while HgCl2 acts as a reducing agent.
Hence, the correct option is A.
Additional Information:
The substances that are reduced (provide oxygen or remove hydrogen) in course of the reaction are called oxidizing agents. These substances oxidize different chemicals in the reaction and are reduced simultaneously.
On the other hand, the substances that are oxidized (remove oxygen or provide hydrogen) are called reducing agents.
Oxidation is defined as a procedure that involves the addition of oxygen or a lost hydrogen.
The reduction is defined as a procedure that involves the addition of hydrogen or a lost oxygen.
Uses of redox reactions:
Combustion of coal to generate electricity.
Rusting of iron objects, in presence of atmospheric oxygen and water.
Note: The possibility to make a mistake is that here SnCl2 is getting oxidized, not reduced and HgCl2 is getting reduced, not oxidized.