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Question

Chemistry Question on coordination compounds

Addition of excess of AgNO3 to an aqueous solution of 1 mole of PdCl2. 4NH3 gives 2 moles of AgCl. The conductivity of this solution corresponds to

A

1 : 2 electrolyte

B

1 : 4 electrolyte

C

1 : 1 electrolyte

D

1 : 3 electrolyte

Answer

1 : 2 electrolyte

Explanation

Solution

[Pb(NH3)4]Cl2[Pb(NH3)4]2++2cI\left[Pb\left(NH_{3}\right)_{4}\right]Cl_{2} \to\left[Pb\left(NH_{3}\right)_{4}\right]^{2+}+2cI^{-}
Itis1:2i.e.,AB2It\, is \,1 : 2\, i.e., AB_{2} type of electrolyte.