Solveeit Logo

Question

Chemistry Question on coordination compounds

Acidified potassium permanganate solution oxidises oxalic acid. The spin-only magnetic moment of the manganese product formed from the above reaction is ______ B.M. (Nearest Integer)

Answer

KMnO4(acidic-medium)+H2C2O4CO2+Mn2+KMnO_4\text {(acidic-medium)} + H_2C_2O_4 → CO_2 + Mn^{2+}

Mn+2Mn^{+2} has 55 unpaired electrons
∴ Spin only magnetic moment
=5(5+2)= \sqrt {5(5+2)}
=5×7= \sqrt {5 \times 7}
=35= \sqrt {35}
5.92 B.M≈ 5.92 \ B.M
6 B.M≈ 6 \ B.M

So, the answer is 66.