Solveeit Logo

Question

Chemistry Question on d -and f -Block Elements

Acidified potassium dichromate reacts with potassium iodide and oxidises it to I2I_2. What is the oxidation state of chromium in the products of the reaction?

A

+4+4

B

+6+6

C

+3+3

D

+2+2

Answer

+3+3

Explanation

Solution

During the reaction K2Cr2O7K_2Cr_2O_7 is converted to Cr2(SO4)3Cr_2(SO_4)_3 K2Cr2O7+7H2SO4+6KI>4K2SO4+Cr2(SO4)3\+7H2O+3I2 {K2Cr2O7 + 7H2SO4 + 6KI -> 4K2SO4 + Cr2(SO4)3 \+ 7H2O + 3I2} In Cr2(SO4)3Cr_2(SO_4)_3, O.S.O.S. of CrCr is +3+3.