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Question

Chemistry Question on d -and f -Block Elements

Acidified K2Cr2O7K_2Cr_2O_7 solution turns green when Na2SO3Na_2SO_3 is added to it. This is due to the formation of

A

CrO42CrO^{2-}_4

B

Cr2(SO3)3Cr_2(SO_3)_3

C

CrSO4CrSO_4

D

Cr2(SO4)3Cr_2(SO_4)_3

Answer

Cr2(SO4)3Cr_2(SO_4)_3

Explanation

Solution

K2Cr2O7+3Na2SO3+4H2SO43Na2SO4+K2SO4+Cr2(SO4)3K _{2} Cr _{2} O _{7}+3 Na _{2} SO _{3}+4 H _{2} SO _{4} \longrightarrow 3 Na _{2} SO _{4}+ K _{2} SO _{4}+ Cr _{2}\left( SO _{4}\right)_{3}