Question
Question: Acidic hydrogen is present in: A. Ethyne B. Ethene C. Benzene D. Ethane...
Acidic hydrogen is present in:
A. Ethyne
B. Ethene
C. Benzene
D. Ethane
Solution
Hint: For solving these types of questions we must know the definition of Acidic hydrogen. Also, we must know the molecular formula of given compounds.
Complete answer:
Acidic hydrogen is, it appears to be released as H+ ion. So if any H-atom is bound to another atom or group of atoms with higher electronegativity than that H-atom is a possible H-atom with acidity.
The acidity of the hydrogen atoms is directly proportional to the s-character.
Chemical compound | Formula | Hybridisation | % s- character |
---|---|---|---|
Ethane | CH3−CH3 | sp3 | 25% |
Ethene | CH2=CH2 | sp2 | 33.33% |
Ethyne | CH≡CH | sp | 50% |
Ethane | C6H6 | sp2 | 33.33% |
Ethyne has the highest percentage of s-character, and most acidic hydrogen atoms are found in ethyne.
We can observe that Ethyne is an alkyne with molecular formula C2H2which contains sp hybridized carbon, Ethene is an alkene with molecular formula C2H4which contains sp2 hybridized carbon, Benzene is a cyclic alkene with molecular formula C6H6 which contains sp2hybridized carbon and Ethane is an alkane with molecular formula C2H6 which contains sp3 hybridized carbon.
As s character is highest in sp hybridized carbon, the electronegativity of carbon is highest because it lies close to the nucleus and removes electrons from hydrogen, releases ions easily and acts as acid.
Therefore, option A is correct and acidic hydrogen is present in ethyne.
Note: For solving these types of questions we must remember the property of sp, sp2and sp3 hybridized carbon atoms and the property of atoms. In this case we saw the ion releasing property of the hydrogen atom.