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Question: Acidic hydrogen is present in: A. Ethyne B. Ethene C. Benzene D. Ethane...

Acidic hydrogen is present in:
A. Ethyne
B. Ethene
C. Benzene
D. Ethane

Explanation

Solution

Hint: For solving these types of questions we must know the definition of Acidic hydrogen. Also, we must know the molecular formula of given compounds.

Complete answer:
Acidic hydrogen is, it appears to be released as H+ ion. So if any H-atom is bound to another atom or group of atoms with higher electronegativity than that H-atom is a possible H-atom with acidity.
The acidity of the hydrogen atoms is directly proportional to the s-character.

Chemical compoundFormulaHybridisation% s- character
EthaneCH3CH3C{H_3} - C{H_3}sp3s{p^3}25%
EtheneCH2=CH2C{H_2} = C{H_2}sp2s{p^2}33.33%
EthyneCHCHCHCHspsp50%
EthaneC6H6{C_6}{H_6}sp2s{p^2}33.33%

Ethyne has the highest percentage of s-character, and most acidic hydrogen atoms are found in ethyne.
We can observe that Ethyne is an alkyne with molecular formula C2H2{C_2}{H_2}which contains spsp hybridized carbon, Ethene is an alkene with molecular formula C2H4{C_2}{H_4}which contains sp2s{p^2} hybridized carbon, Benzene is a cyclic alkene with molecular formula C6H6{C_6}{H_6} which contains sp2s{p^2}hybridized carbon and Ethane is an alkane with molecular formula C2H6{C_2}{H_6} which contains sp3s{p^3} hybridized carbon.
As s character is highest in spsp hybridized carbon, the electronegativity of carbon is highest because it lies close to the nucleus and removes electrons from hydrogen, releases ions easily and acts as acid.

Therefore, option A is correct and acidic hydrogen is present in ethyne.

Note: For solving these types of questions we must remember the property of spsp, sp2s{p^2}and sp3s{p^3} hybridized carbon atoms and the property of atoms. In this case we saw the ion releasing property of the hydrogen atom.