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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Acetophenone (PhCOCH3)(Ph-\overset{\underset{||}{O}}{C}- CH_3) is prepared in the laboratory by

A

B

C

D

PhCOCl+CH4AlCl3Ph-\overset{\underset{||}{O}}{C}- Cl +CH_4 \xrightarrow {AlCl_3}

Answer

Explanation

Solution

Aromatic ketones can be prepared by Friedel-Craft's acylation or benzoylation. Acetophenone is prepared by the action of benzene with acetyl chloride in the presence of anhydrous AlCl3AlCl _{3}. In this reaction the HH-atom of benzene is replaced by acyl (- COCH3COCH _{3} ) group.
This reaction is an example of electrophilic substitution reaction.