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Question

Chemistry Question on Amines

Acetamide and ethylamine can be distinguished by reacting with

A

aq. HCI and heat

B

aq. NaOH and heat

C

acidified KMn04KMn0_4

D

bromine water

Answer

aq. NaOH and heat

Explanation

Solution

When acetamide is heated with a NaOH it forms NH3NH_3 gas but ethylamine cannot form NH3NH_3. CH3CONH2+H2ONaOHCH3COONa+NH3CH_3 CONH_2 + H_2 O \xrightarrow {NaOH} CH_3 COONa + NH_3 CH3CH2NH2+H2ONaOHCH_3 CH_2 NH_2 + H_2 O \xrightarrow {NaOH} No reaction