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Question

Chemistry Question on Thermodynamics

According to the first law of thermodynamics, ΔU=q+w\Delta U = q + w. In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

A

At constant temperature : qwq - -w

B

When no work is done : ΔU=q\Delta U = q

C

In gaseous system : ΔU=q+PΔV\Delta U = q + P\Delta V

D

When work is done by the system : ΔU=q+w\Delta U = q + w

Answer

When work is done by the system : ΔU=q+w\Delta U = q + w

Explanation

Solution

When work is done by the system, ΔU=qw\Delta U=q-w.