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Question: A white solid X on heating gives a white solid Y and an acidic gas Z. Gas Z is also given out when X...

A white solid X on heating gives a white solid Y and an acidic gas Z. Gas Z is also given out when X reacts with an acid. The compound Y is also formed if caustic soda is left open in the atmosphere. X, Y and Z are

XYZ
ANaHCO3NaHCO_{3}Na2CO3Na_{2}CO_{3}CO2CO_{2}
BNa2CO3Na_{2}CO_{3}NaOHCO2CO_{2}
CNa2CO3Na_{2}CO_{3}NaHCO3NaHCO_{3}CO2CO_{2}
DNaOHNaHCO3NaHCO_{3}CO2CO_{2}
A

(A) NaHCO3, Na2CO3, CO2

A

(B) Na2CO3, NaOH, CO2

A

(C) Na2CO3, NaHCO3, CO2

A

(D) NaOH, NaHCO3, CO2

Explanation

Solution

: 2NaHCO3(X)Na2CO3(Y)+CO2(Z)+H2O\underset{(X)}{2NaHCO_{3}} \rightarrow \underset{(Y)}{Na_{2}CO_{3}} + \underset{(Z)}{CO_{2}} + H_{2}O

NaHCO3(X)+HClNaCl+CO2(Z)+H2O\underset{(X)}{NaHCO_{3}} + HCl \rightarrow NaCl + \underset{(Z)}{CO_{2}} + H_{2}O

2NaOH+CO2(atmosphere)Na2(Y)CO3+H2O2NaOH\underset{(atmosphere)}{+ CO_{2}} \rightarrow \underset{(Y)}{Na_{2}}CO_{3} + H_{2}O