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Question

Chemistry Question on Qualitative Analysis

A white precipitate was formed when BaCl2 was added to water extract of an inorganic salt. Further, a gas 'X' with characteristic odour was released when the formed white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt is

A

I-

B

SO32SO^{2-}_3

C

S2-

D

NO2NO^{-}_2

Answer

SO32SO^{2-}_3

Explanation

Solution

The correct answer is (B) : SO32SO^{2-}_3
Anion is
SO32SO^{2-}_3
BaSO3dil.HCLSO2BaSO_3 \stackrel{dil.HCL}{→} SO_2 ↑
X (gas)
Gas is released with smell of burning sulphur.