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Question: A vessel is partitioned in two equal halves by a fixed dia thermic separator. Two different ideal ga...

A vessel is partitioned in two equal halves by a fixed dia thermic separator. Two different ideal gases are filled in left (L) and right (R) halves. The rms speed of the molecules in L part is equal to the mean speed of molecules in the R part. Then the ratio of the mass of a molecule in L part to that of a molecule in R part is

A

32\sqrt{\frac{3}{2}}

B

π/4\sqrt{\pi/4}

C

2/3\sqrt{2/3}

D

3π/83\pi/8

Answer

3π/83\pi/8

Explanation

Solution

Root means square velocity of molecule in left partvrms=3KTmLv_{rms} = \sqrt{\frac{3KT}{m_{L}}}

Mean or average speed of molecule in right part vav=8πKTmRv_{av} = \sqrt{\frac{8}{\pi}\frac{KT}{m_{R}}}

According to problem 3KTmL=8πKTmR\sqrt{\frac{3KT}{m_{L}}} = \sqrt{\frac{8}{\pi}\frac{KT}{m_{R}}}

3mL=8πmR\frac{3}{m_{L}} = \frac{8}{\pi m_{R}}mLmR=3π8\frac{m_{L}}{m_{R}} = \frac{3\pi}{8}.