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Question: A vessel has 6 g of hydrogen at pressure P and temperature 500 K. A small hole is made in it so that...

A vessel has 6 g of hydrogen at pressure P and temperature 500 K. A small hole is made in it so that hydrogen leaks out. How much hydrogen leaks out if the final pressure is P/2 and temperature falls to 300 K –

A

2 g

B

3 g

C

4 g

D

1g

Answer

1g

Explanation

Solution

PV=mMRTPV = \frac{m}{M}RT

Initially PV = 6MR×500\frac{6}{M}R \times 500

P2V=6xM\frac{P}{2}V = \frac{6–x}{M} R × 300(if x g gas leaks out)

Hence, 2 = 66x×53\frac{6}{6–x} \times \frac{5}{3}

x = 1 gm