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Question: A student adds 0.1-molar HCL to 0.1-molar KOH until the resulting solution is neutral. When this sol...

A student adds 0.1-molar HCL to 0.1-molar KOH until the resulting solution is neutral. When this solution is evaporated to dryness. The substance that remains can be correctly described as which of the following?
I) a white, crystalline solid
II) A covalent solid
III) A water-soluble salt
A) I only
B) II only
C) III only
D) I and III only
E) I, II and III only

Explanation

Solution

The chemical reaction of acid and base to form a salt and water is known as the neutralization reaction. The strong acid reacts with the strong base and neutralizes each other such that the  pH \text{ pH } solution is equal to 7. This neutralization reaction results in the neutral salt.

Complete step by step answer:
A chemical reaction in which the acid and base quantitatively react with each other to form salt and water is known as the neutralization reaction. In the neutralization reaction, the proton  H+ \text{ }{{\text{H}}^{\text{+}}}\text{ } (from acid) reacts with the hydroxide ion  OH \text{ O}{{\text{H}}^{-}}\text{ } to form a water molecule. An acid-base neutralization reaction is as shown below,
 Acid + Base  Salt + water \text{ Acid + Base }\to \text{ Salt + water }
The  pH \text{ pH } and the strength of salt depends on the strength of the acid and base undergoing the neutralization reaction.
We have given that the  0.1 M HCl \text{ 0}\text{.1 M HCl } reacts with the 0.1 M KOH \text{ 0}\text{.1 M KOH }. The hydrochloric acid is a strong acid. Similarly, the potassium hydroxide is a strong base.
In a neutralization reaction of a strong base with the strong acid results in the neutral solution having pH = 7 \text{ pH = 7 }.
The neutralization reaction between the  0.1 mole \text{ 0}\text{.1 mole } of hydrochloric acid and the  0.1 mole \text{ 0}\text{.1 mole }potassium hydroxide given as follows,
 HCl + KOH  KCl + H2\text{ HCl + KOH }\to \text{ KCl + }{{\text{H}}_{\text{2}}}\text{O }
The product that is potassium chloride  KCl \text{ KCl }is a white, crystalline solid. It is an ionic salt of potassium ion  K+ \text{ }{{\text{K}}^{\text{+}}}\text{ } and chloride ion Cl \text{ C}{{\text{l}}^{-}}\text{ }. Since it is an ionic salt, in aqueous solution it dissociates into its corresponding potassium and chloride ions. The reaction is as follows,
 KCl  K+ + Cl \text{ KCl }\to \text{ }{{\text{K}}^{\text{+}}}\text{ + C}{{\text{l}}^{-}}\text{ }
Potassium chloride is an odourless and white or colourless vitreous crystalline salt. It readily dissolves in water and tastes like table salt. Potassium chloride is ionic salt. It is not a covalent compound.
Thus, here the obtained salt is white, crystalline, and water-soluble.

Hence, (D) is the correct option.

Note: The nature of salt and  pH \text{ pH } the solution depend on the strength of acid and base. This is given as follows,

Strength of AcidStrength of BaseResultant  pH \text{ pH }
StrongStrong 7 \text{ 7 }
Strongweak <\text{ }<\text{7 }
weakStrong >\text{ }>\text{7 }
weakweakIf, Ka>Kb  pH <7  Ka=Kb  pH =7  Ka<Kb  pH >7 \begin{aligned} & \text{ }{{\text{K}}_{\text{a}}}>{{\text{K}}_{\text{b}}}\text{ }\Rightarrow \text{ pH }<\text{7} \\\ & \text{ }{{\text{K}}_{\text{a}}}\text{=}{{\text{K}}_{\text{b}}}\text{ }\Rightarrow \text{ pH =7} \\\ & \text{ }{{\text{K}}_{\text{a}}}<{{\text{K}}_{\text{b}}}\text{ }\Rightarrow \text{ pH }>\text{7} \\\ \end{aligned}.