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Question: A stationary cylinder of oxygen used in a hospital has the following characteristics at room tempera...

A stationary cylinder of oxygen used in a hospital has the following characteristics at room temperature 300k, gauge pressure138×107Pa1 \cdot 38 \times {10^7}{\text{Pa}}, volume16L16L. If the flow area, measured at atmospheric pressure, is constant 24Lmin.2 \cdot 4\dfrac{L}{{\min .}} the cylinder last nearly for,
A) 5h
B) 10h
C) 15h
D) 20h

Explanation

Solution

The pressure of the cylinder after the cylinder gets empty is equal to the atmospheric pressure as the cylinder is getting empty at room temperature. The volume of the cylinder is the flow of the cylinder in the time taken by the cylinder to get empty.

Formula used: The formula for the isothermal process is given by P1V1=P2V2{P_1}{V_1} = {P_2}{V_2} where P1{P_1} is the initial pressure of the cylinder V1{V_1} is the initial volume of the cylinder P2{P_2} is the final pressure of the cylinder and V2{V_2}is the final volume of the cylinder.

Step by step solution:
It is given that the initial pressure is equal to 138×107Pa1 \cdot 38 \times {10^7}{\text{Pa}} also the initial volume is 16L16L also the
Final pressure will be atmospheric pressure ofP2=105Pa{P_2} = {10^5}Pa and final volume will be equal to V2=24t{V_2} = 2 \cdot 4t where t is the time taken to empty the cylinder.
In the isothermal process we get,
P1V1=P2V2\Rightarrow {P_1}{V_1} = {P_2}{V_2}
Replace the value ofP1{P_1},P2{P_2} and V1{V_1} we get
(138×107)(16)=(105)V2\Rightarrow \left( {1 \cdot 38 \times {{10}^7}} \right)\left( {16} \right) = \left( {{{10}^5}} \right){V_2}
24t=(138×107)(16)(105)\Rightarrow 2 \cdot 4t = \dfrac{{\left( {1 \cdot 38 \times {{10}^7}} \right)\left( {16} \right)}}{{\left( {{{10}^5}} \right)}}
24t=(138×102)(16)\Rightarrow 2 \cdot 4t = \left( {1 \cdot 38 \times {{10}^2}} \right)\left( {16} \right)
24t=2208\Rightarrow 2 \cdot 4t = 2208
t=220824\Rightarrow t = \dfrac{{2208}}{{2 \cdot 4}}
t=920min.\Rightarrow t = 920\min .
Converting minutes into hours.
t=92060h\Rightarrow t = \dfrac{{920}}{{60}}h
t=15.3h\Rightarrow t = 15.3h
t15h\Rightarrow t \simeq 15h
So the time taken by the cylinder to empty itself ist=15ht = 15h.

The correct option for this problem is option C.

Additional information: The isothermal temperature means that the temperature is always constant. The work done for isothermal process is given by W=P1V1ln(V2V1)W = {P_1}{V_1}\ln \left( {\dfrac{{{V_2}}}{{{V_1}}}} \right) where W is the work done P1{P_1} is the initial pressure V1{V_1} is the initial volume of the cylinder and V2{V_2} is the final volume of the cylinder.

Note: The relation for the isothermal process is based on the property of constant temperature. The ideal gas equation is the main equation from which the isothermal process relation of the body is taken out by keeping temperature as constant.