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Question

Chemistry Question on d block elements

A solution of colourless salt HH on boiling with excess NaOHNaOH produces a non-flammable gas. The gas evolution ceases after sometime. Upon addition of ZnZn dust to the same solution, the gas evolution restarts. The colourless salt(s) HH

A

NH4NO3NH_4 NO_3

B

NH4NO2NH_4 NO_2

C

NH4ClNH_4 Cl

D

(NH4)2SO4(NH_4)_2 SO_4

Answer

NH4NO2NH_4 NO_2

Explanation

Solution

NH4NO3+NaOHNaNO3+NH3+H2ONH_4 NO_3 + NaOH \longrightarrow \, NaNO_3 + NH_3 + H_2 O
NH4NO2+NaOHNaNO2+NH3+H2ONH_4 NO_2 + NaOH \longrightarrow \, NaNO_2 + NH_3 + H_2 O