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Question: A solution of A is mixed with an equal volume of solution of B containing the same no. of moles & fo...

A solution of A is mixed with an equal volume of solution of B containing the same no. of moles & following reaction occurs A + B ¾® C. At the end of 1 hr, A is 75% reacted. How much of A will be left unreacted at the end of 2 hr if the reaction is 1st order in A & zero order in B –

A

0%

B

12.5%

C

6.25%

D

25%

Answer

6.25%

Explanation

Solution

w.r.t A reaction follows 1st order i.e. half life is constant.

Remaining A after 2 half life i.e. 1 hr = 25%

Remaining A after 3 half life i.e.1121\frac{1}{2}hr = 12.5 %

Remaining A after 4 half life i.e. 2 hr = 6.25%