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Question

Chemistry Question on Electrochemistry

A solution contains Fe2+,Fe3+{Fe^{2+}, Fe^{3+}} and II^- ions. This solution was treated with iodine at 35C.E{ 35^{\circ} C. E^{\circ}} for Fe3+/Fe2+{Fe^{3+} /Fe^{2+}} is +0.77V+0.77 \, V and EE^{\circ} for I2/2I=0.536V.I_2/2I^- = 0.536 \, V. The favourable redox reaction is-

A

Fe2+{Fe^{2+}} will be oxidized to Fe3+ {Fe^{3+}}

B

I2I_2 will be the reduced to II^-

C

There will be no redox reaction

D

II^- will be oxidized to I2I_2

Answer

II^- will be oxidized to I2I_2

Explanation

Solution

2Fe=3+2I>I2+2Fe=2{2Fe^{=3} + 2I^- -> I_2 + 2Fe^{=2}}