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Question: A single electron orbits a stationary nucleus of charge +*Ze*, where *Z* is a constant. It requires ...

A single electron orbits a stationary nucleus of charge +Ze, where Z is a constant. It requires 47.2 eV to excited electron from second Bohr orbit to third Bohr orbit. Find the value of Z

A

2

B

5

C

3

D

4

Answer

5

Explanation

Solution

Excitation energy of hydrogen like atom for n2n1n_{2} \rightarrow n_{1}

ΔE=13.6Z2(1n121n22)eV\Delta E = 13.6Z^{2}\left( \frac{1}{n_{1}^{2}} - \frac{1}{n_{2}^{2}} \right)eV

47.2=13.6Z2(122132)=13.6×536Z247.2 = 13.6Z^{2}\left( \frac{1}{2^{2}} - \frac{1}{3^{2}} \right) = 13.6 \times \frac{5}{36}Z^{2}

Z2=47.2×3613.6×5=24.98~25Z^{2} = \frac{47.2 \times 36}{13.6 \times 5} = 24.98\widetilde{-}25

Z = 5