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Question

Question: A sample of gas occupies \[{\text{240 c}}{{\text{m}}^{\text{3}}}\] at \[{\text{37}}{{\text{ }}^{\tex...

A sample of gas occupies 240 cm3{\text{240 c}}{{\text{m}}^{\text{3}}} at 37 oC{\text{37}}{{\text{ }}^{\text{o}}}{\text{C}} and 100 kPa{\text{100 kPa}}. How many moles of gas are present in the sample?
A. 9.32 ×1039.32{\text{ }} \times {10^{ - 3}}
B. 1.24 ×1031.24{\text{ }} \times {10^{ - 3}}
C. 0.07810.0781
D. 78.178.1

Explanation

Solution

We must know that the ideal gas law is the empirical relationship between volume and the amount of gas. Therefore, we can solve this question with the ideal gas equation
PV = nRT{\text{PV = nRT}}
Formula used:
The ideal gas equation is
PV = nRT{\text{PV = nRT}}
Where,
PP is pressure
VV is volume
RR is gas constant
TT is temperature
nn is the number of moles

Complete step by step answer:
In the question, they have given

P=100k Pa=0.987atm (1atm=101.325kPa)  P = 100k \\\ {P_a} = 0.987atm{\text{ }}\left( {\because 1atm = 101.325kPa} \right) \\\

V=240cm3=0.24L (Q1cm3=103L)V = 240c{m^3} = 0.24L{\text{ }}(Q1c{m^3} = {10^{ - 3}}L)
T=37oC=273.15+37=310.15KT = {37^o}C = 273.15 + 37 = 310.15K
R= Gas constant =0.0821L.atm/mol.K{\text{0}}{\text{.0821L}}{\text{.atm/mol}}{\text{.K}}
According to ideal gas law,PV = nRT{\text{PV = nRT}}, where ‘n’ is the number of moles of the molecules.
Therefore, we can substitute the value of pressure (P), volume (V) and temperature (T) in the ideal gas equation; we can find the value of ‘n’
PV=nRTPV = nRT
0.987×0.24=n×0.0821×3100.987 \times 0.24 = n \times 0.0821 \times 310
n=9.3×103moln = 9.3 \times {10^{ - 3}}{\text{mol}}
Therefore, option A. 9.32 ×1039.32{\text{ }} \times {10^{ - 3}} is the correct among the following.

Note:
We can define the mole as the amount of a substance that contains exactly 6.02214076 ×1023  6.02214076{\text{ }} \times {10^{23}}\;‘elementary entities’ of the given substance that can be atoms, molecules, monatomic/polyatomic ions, and other particles (such as electrons).
The number 6.02214076 ×1023  6.02214076{\text{ }} \times {10^{23}}\; is popularly known as the Avogadro constant and is often denoted by the symbol ‘NA{N_A}’.
Also one mole of carbon-12 (12C^{12}C) sample will have a mass of exactly equal to 12 grams and will contain 6.02214076 ×1023  6.02214076{\text{ }} \times {10^{23}}\; (NA{N_A}) number of 12C^{12}C atoms. The number of moles of a given substance can also be represented by the following formula:
n = N/NA{\text{n = N/}}{{\text{N}}_{\text{A}}}
Where ‘n’ is the number of moles of the substance (or elementary entity), N is the total number of elementary entities in the sample, and NA{N_A} is the Avogadro constant.