Solveeit Logo

Question

Chemistry Question on Rate of a Chemical Reaction

A sample of 0.42mg233UF60.42 \,mg \,{ }^{233} UF _{6} shows an activity of 9.88×1049.88 \times 10^{4} count per second. Its t1/2t_{1 / 2} is

A

5.13×1012yr5.13 \times 10^{12} yr

B

1.628×105yr1.628 \times 10^{5} yr

C

2.94×109yr2.94 \times 10^{-9} yr

D

2.35×108yr2.35 \times 10^{8} yr

Answer

1.628×105yr1.628 \times 10^{5} yr

Explanation

Solution

Molecular mass of UF6=233+19×6=347U F_{6}=233+19 \times 6=347 dNdt=kN\frac{d N}{d t} =k N 9.88×104=k×0.42×103×6.023×10233479.88 \times 10^{4} =k \times \frac{0.42 \times 10^{-3} \times 6.023 \times 10^{23}}{347} k=1.35×1013\therefore k =1.35 \times 10^{-13} k=0.693t1/2k =\frac{0.693}{t_{1 / 2}} [\because Radioactive changes follow Ist order kinetics.] or t1/2=0.6931.35×1013st_{1 / 2} =\frac{0.693}{1.35 \times 10^{-13}} s =5.13×1012s=5.13 \times 10^{12} s =1.628×105yr.=1.628 \times 10^{5} \,yr .