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Question

Physics Question on The Kinetic Theory of Gases

A sample contains a mixture of helium and oxygen gas. The ratio of root mean square speed of helium and oxygen in the sample is:

A

132\frac{1}{\sqrt{32}}

B

222\sqrt{2}

C

14\frac{1}{4}

D

122\frac{1}{2\sqrt{2}}

Answer

222\sqrt{2}

Explanation

Solution

The root mean square speed (VrmsV_{\text{rms}}) is given by:

Vrms=3RTMwV_{\text{rms}} = \sqrt{\frac{3RT}{M_w}}

where MwM_w is the molar mass of the gas.

The ratio of root mean square speeds of helium (VHeV_{\text{He}}) and oxygen (VO2V_{\text{O}_2}) is:

VO2VHe=Mw,HeMw,O2\frac{V_{\text{O}_2}}{V_{\text{He}}} = \sqrt{\frac{M_{w,\text{He}}}{M_{w,\text{O}_2}}}

Substituting the values:

  • Mw,He=4g/molM_{w,\text{He}} = 4 \, \text{g/mol}
  • Mw,O2=32g/molM_{w,\text{O}_2} = 32 \, \text{g/mol}

VO2VHe=432=122\frac{V_{\text{O}_2}}{V_{\text{He}}} = \sqrt{\frac{4}{32}} = \frac{1}{2\sqrt{2}}

The ratio VHe/VO2V_{\text{He}} / V_{\text{O}_2} is:

VHeVO2=221\frac{V_{\text{He}}}{V_{\text{O}_2}} = \frac{2\sqrt{2}}{1}