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Question

Chemistry Question on coordination compounds

A sample containing 1.0 mole of an ideal gas is expanded reversibly and isothermally to ten times its original volume in two separate experiments. The expansion is carried out at 300 K and 600 K, respectively. Choose the correct option.

A

(A) Work done at 600 K is twice the work done at 300 K.

B

(B) Work done at 600 K is 20 times the work done at 300 K.

C

(C) Work done at 300 K is twice the work done at 600 K.

D

(D) ∆ U ≠ 0 in both cases.

Answer

(A) Work done at 600 K is twice the work done at 300 K.

Explanation

Solution

Explanation:
For an ideal gas, the work of reversible expansion under isothermal conditions can be calculated by using the expansion w = -nRT ln Vf/Vi.W600KW300K=1×R×600×ln⁡1011×R×300×ln⁡101=2In isothermal expansion, ΔU=0