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Question

Chemistry Question on Qualitative Analysis

A reagent which gives brilliant red precipitate with Nickel ions in basic medium is

A

sodium nitroprusside

B

neutral FeCl3_3

C

meta-dinitrobenzene

D

dimethyl glyoxime

Answer

dimethyl glyoxime

Explanation

Solution

The reagent that gives a brilliant red precipitate with Nickel ions (Ni2+\text{Ni}^{2+}) in a basic medium is dimethyl glyoxime (dmg). When Ni2+\text{Ni}^{2+} reacts with dimethyl glyoxime, it forms a complex that produces a bright red precipitate. The reaction is as follows:
Ni2++dmg[Ni(dmg)2](Rosy red/Bright Red precipitate)\text{Ni}^{2+} + \text{dmg} \rightarrow [\text{Ni}(\text{dmg})_2] \, \, (\text{Rosy red/Bright Red precipitate})

Thus, the correct answer is dimethyl glyoxime.

The Correct Answer is: dimethyl glyoxime