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Question: A reaction is at equilibrium at \(100^{o}C\) and the enthalpy change for the reaction is \(42.6kJmol...

A reaction is at equilibrium at 100oC100^{o}C and the enthalpy change for the reaction is 42.6kJmol142.6kJmol^{- 1} What will be the value of ΔSinJK1mol1?\Delta SinJK^{- 1}mol^{- 1?}

A

120

B

426.2426.2

C

373.1373.1

D

114.2114.2

Answer

114.2114.2

Explanation

Solution

: ΔG=ΔHTΔS\Delta G = \Delta H - T\Delta S

At equilibrium, ΔG=0,ΔH=TΔS\Delta G = 0,\Delta H = T\Delta S

ΔS=ΔHT=42600Jmol1373K=114.2JK1mol1\Delta S = \frac{\Delta H}{T} = \frac{42600Jmol^{- 1}}{373K} = 114.2JK^{- 1}mol^{- 1}