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Question

Chemistry Question on Chemical Kinetics

A piece of wood from an' archaeological sample has 5.05.0 counts min1\min ^{-1} per gram of C14C-14, while a fresh sample of wood has a count of 15.0min1g115.0 \,min ^{-1} \,g ^{-1}. If half-life of C14C-14 is 5770yr5770\, yr, the age of the archaeological sample is

A

8,500 years

B

9,200 years

C

10,000 years

D

11,000 years

Answer

9,200 years

Explanation

Solution

Age of archaeological sample,
t=2.303klog(N0N)t=\frac{2.303}{k} \log \left(\frac{N_{0}}{N}\right)
(Here, N0=N_{0}= initial activity,
N=N= remaining activity)
and
k=0.693t1/2k=\frac{0.693}{t_{1 / 2}}
(where t1/2=t_{1 / 2}= half-life)
=0.6935770yr1=\frac{0.693}{5770} yr ^{-1}
t=2.303×57700.693log(155)\therefore t=\frac{2.303 \times 5770}{0.693} \log \left(\frac{15}{5}\right)
=19175.0log3yr=19175.0 \,\log \,3 \,yr
=9148yr9200Yr=9148 \,yr \approx 9200 \,Yr