Question
Chemistry Question on Developments Leading to the Bohr’s Model of Atom
A photon of wavelength 4×10–7m strikes on metal surface, the work function of the metal being 2.13 eV. Calculate:
- the energy of the photon (eV)
- the kinetic energy of the emission, and
- the velocity of the photo electron (1 eV=1.6020×10–19J).
(i) Energy (E) of a photon = hν = λhc
Where,
h = Planck's constant = 6.626×10-34 Js
c = velocity of light in vacuum = 3×108 m/s
λ = wavelength of photon = 4 × 10-7 m
Substituting the values in the given expression of E:
E=4×10−7(6.626×10−34)(3×108)
E=4.9695×10−19 J
Hence, the energy of the photon is 4.97×1019J.
(ii) The kinetic energy of emission KE is given by
KE=hv−hv0
KE=(E−W) eV
KE=(3.1020−2.13) eV
KE=0.9720 eV
Hence, the kinetic energy of emission is 0.97 eV.
(iii) The velocity of a photoelectron (V) can be calculated by the expression,
21mv2=hv−hv0
⇒ v=m2(hv−hv0)
Where,
(hv−hv0) is the kinetic energy of emission in Joules and
'm' is the mass of the photoelectron.
Substituting the values in the given expression of v:
v=9.10939×10−31kg2×(0.9720×1.6020×10−19)J
v=0.3418×1012 m2s−2
v=5.84×105 ms−1
Hence, the velocity of the photoelectron is 5.84×105 ms−1.