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Question: A neutral atom of an element has \(2K,8L{\text{ and }}5M\) electrons. What is the maximum number of ...

A neutral atom of an element has 2K,8L and 5M2K,8L{\text{ and }}5M electrons. What is the maximum number of electrons having the same spin?
(a) 55
(b) 88
(c) 99
(d) 33

Explanation

Solution

The orientation of an electron in an orbital is decided by its spin axis. An electron can spin in any two directions, either clockwise (up) or anticlockwise (down). If up spin is taken as +12 + \dfrac{1}{2}, then down will be 12 - \dfrac{1}{2}.

Complete step by step answer:
Spin of an electron is given by a fourth quantum number, denoted by ms or s{m_s}{\text{ or }}s. By Pauli’s exclusion principle, an orbital can have only two electrons, and those two must have opposite spin. That’s why the value of one spin is taken as +12 + \dfrac{1}{2}, and value for other is taken as 12 - \dfrac{1}{2}. K,L,M{\text{K,L,M}} are the shells of an atom with KK being the first shell, and so on. By the formula of 2n22{n^2}, where nn is the shell number, KK can have maximum 2(1)2=22{\left( 1 \right)^2} = 2 electrons, MM can have maximum 2(2)2=82{\left( 2 \right)^2} = 8 electrons, and LL can have maximum 2(3)2=182{\left( 3 \right)^2} = 18 electrons. As Given in the question, an element has 2K,8L and 5M2K,8L{\text{ and }}5M electrons means, this element will have total 2+8+5=152 + 8 + 5 = 15 electrons, and since the number of electrons in a neutral atom is equal the atomic number, so, this element is Phosphorus with atomic number 15{\text{15}}. To calculate the spin of its electrons, its electronic configuration should be observed, which is 1s22s22p63s23p31{s^2}2{s^2}2{p^6}3{s^2}3{p^3}. Filling out the electrons in the respective shells according the electronic configuration:

\uparrow \downarrow\uparrow \downarrow\uparrow \downarrow\uparrow \downarrow\uparrow \downarrow\uparrow \downarrow\uparrow\uparrow\uparrow

1s21{s^2} 2s22{s^2} 2p62{p^6} 3s23{s^2} 3p33{p^3}
From the electronic configuration, it can be seen that 99 electrons have the same up spin.

So, the correct answer is Option C .

Note:
It should be carefully observed that there are 6{\text{6}} electrons also which have the same down spin but it was not there in the option, so it was not considered. Spin of electrons is also related to spin angular momentum, which is given by S=s(s+1)h2π, where h is Planck’s constant and s=±12S = \sqrt {s\left( {s + 1} \right)} \dfrac{h}{{2\pi }}{\text{, where }}h{\text{ is Planck's constant and }}s = \pm \dfrac{1}{2}.