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Question

Chemistry Question on Hydrocarbons

A mixture of three gases, ethane, ethene and ethyne are passed through ammoniacal solution of cuprous chloride. The emergent gas(es) after it was passed through solution contained

A

ethane only

B

ethane and ethene

C

ethane and ethyne

D

ethyne only.

Answer

ethane and ethene

Explanation

Solution

Ethyne having acidic hydrogens reacts with Cu2Cl2Cu_2Cl_2. CHCH+Cu2Cl2CuCCCu+2HClCH \equiv CH + Cu_{2}Cl_{2} \to Cu - C \equiv C - Cu + 2HCl Ethane and ethene remain unreacted and come out of the solution.