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Question

Chemistry Question on Equilibrium

A mixture of hydrogen and oxygen contains 40% hydrogen by mass when the pressure is 2.2 bar. The partial pressure of hydrogen is _______ bar. (Nearest integer)

Answer

40% w/w hydrogen gas is given in mixture of H2H_2 and oxygen.
Wt. of H2H_2 = 40 g
Wt. of O2O_2 = 60 g
XH2=nH2nH2+nO2X_{H2}=\frac {n_{H_2}}{n_{H_2}+n_{O_2}}

=402402+6032=\frac {\frac {40}{2}}{\frac {40}{2}+\frac {60}{32}}

=2020+1.875=\frac {20}{20+1.875}

=2021.875=\frac {20}{21.875}
=0.914=0.914
PH2=XH2×PTP_{H_2}=X_{H_2}×PT
PH2=0.914×2.2P_{H_2}=0.914×2.2
PH2=2.01P_{H_2}=2.01
PH22P_{H_2}≃2 bar

So, the answer is 22 bar.