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Question: A mixture of gases at NTP for which \(\Upsilon = 1.5\) is suddenly compressed to \(\dfrac{1}{9}th\) ...

A mixture of gases at NTP for which Υ=1.5\Upsilon = 1.5 is suddenly compressed to 19th\dfrac{1}{9}th of its original volume. The final temperature of mixture is:
A. 300C{300^ \circ }C
B. 546C{546^ \circ }C
C. 420C{420^ \circ }C
D. 872C{872^ \circ }C

Explanation

Solution

Hint: Remember to consider the initial temperature of the mixture as 273K also use the given statement to find the final volume of the mixture and use the information to find the final temperature of the mixture.

Complete answer:
We know Initial temperature (T1) = 0°C = 273 K
Let Initial volume (V1) = V
Final volume (V2) = V/9
Υ=1.5\Upsilon = 1.5
According to adiabatic process, PVΥP{V^\Upsilon }= Constant
Since P = T/V
Therefore TVVΥ1=c\dfrac{T}{V}{V^{\Upsilon - 1}} = c
TVΥ1=cT{V^{\Upsilon - 1}} = c
For initial condition T1V1Υ1=c{T_1}V_1^{\Upsilon - 1} = c (equation 1)
For final condition T2V2Υ1=c{T_2}V_2^{\Upsilon - 1} = c (equation 2)
Equating equation 1 and 2
T1V1Υ1=T2V2Υ1{T_1}V_1^{\Upsilon - 1} = {T_2}V_2^{\Upsilon - 1}
According to question V2=V119{V_2} = {V_1}\dfrac{1}{9}
Therefore T2=T1(V1V2)Υ1{T_2} = {T_1}{(\dfrac{{{V_1}}}{{{V_2}}})^{\Upsilon - 1}}
T1(9)0.5\Rightarrow {T_1}{(9)^{0.5}}
3×273\Rightarrow 3 \times 273
819K=546C\Rightarrow 819K= {546^ \circ }C

Therefore the final temperature of the mixture is 546C{546^ \circ }C.

Note: The concept of Adiabatic process is defined as the thermodynamic process in which there is no exchange of heat from the system to its surrounding neither during expansion nor during compression. Adiabatic processes can be reversible or irreversible. But for adiabatic processes to occur there are some conditions in which an adiabatic process can take place is that the system must be perfectly insulated from the surrounding and also the process must be carried out quickly so that there is sufficient amount of time for heat transfer to take place.
The Adiabatic process Equation is PVΥP{V^\Upsilon }= Constant here P is the pressure of the system, V is the volume of the system and Υ\Upsilon is the adiabatic index which is defend as the ratio of heat capacity at constant pressure CP{C_P} to heat capacity at constant volume CV{C_V}.